At the inception of our project, no study had examined particle fluxes in the Subantarctic Zone (SAZ) of the Southern Ocean, despite the fact that the SAZ represents a large portion of the total area of the Southern Ocean, serve as a strong sink for atmospheric (~1G t C yr-1 [Metzl et al., 1999]), and is central to hypotheses linking particle fluxes and climate change [Francois et al., 1997; Kumar et al., 1995; Sigman et al., 1999]. The SAZ serves as an interface between the cold nutrient-rich waters to its south and the nutrient-depleted subtropical gyres to its north. SAZ upper layers are marked by a thick layer of relatively homogenous Subantarctic Mode Water (SAMW), which overlies Antarctic Intermediate Water (AAIW). Both water masses are subducted northward beneath the subtropical gyres. Thus particles leaving the surface in these regions contribute to carbon redistribution via both the fraction that reaches the deep sea by settling and the fraction that is remineralized within SAMW or AAIW and subsequently subducted. The SAZ exhibits surface water carbon dioxide partial pressures well below atmospheric equilibrium, but PFZ waters are closer to atmospheric equilibrium in this sector [Metal et al., 1999; Poppet al., 1999]. The relative physical and biological contributions to these carbon dioxide partial pressure variations are unclear, but it is important to determine them because physical and biological carbon dioxide transfers are expected to show different responses to climate change [ Matear et al., 1999; Sarmiento and LeQuere, 1996]. For these reasons we focused on the SAZ and, for comparative purposes, on the PFZ to its south. We measured particle fluxes using moored sinking particle traps at three sites in the SAZ, in the PFZ, and beneath the Subantarctic Front (SAF), which separates them. This record describes particle flux data collected between 2000 and 2001. The NetCDF data contains the following variables. Please note not all variables are supplied in all files, specifically there are not uncertainty estimates and no quality control flags for this data. -----DATA DICTIONARY----- Name, description, units, standard name TIME, time, YYYY-MM-DD, time of sample midpoint TIME_START, time sample open, YYYY-MM-DD, time sample open NOMINAL_DEPTH, depth, m, nominal depth LATITUDE, latitude, degrees_north, latitude of anchor LONGITUDE, longitude, degrees_east, longitude of anchor pressure_actual, actual, dbar, actual pressure sample, sample number, 1, sample number sample_quality_control, quality flag for sample number, unitless, quality flag for sample number mass_flux, <1mm, mg m-2 d-1, particulate total mass flux mass_flux_uncertainty, uncertainty for particulate total mass flux, mg m-2 d-1,), uncertainty for particulate total mass flux mass_flux_quality_control, quality flag for particulate total mass flux, unitless, quality flag for particulate total mass flux SAL_BRINE, supernatant, 1, sample supernatant practical salinity SAL_BRINE_uncertainty, uncertainty for sample supernatant practical salinity, 1, uncertainty for sample supernatant practical salinity SAL_BRINE_quality_control, quality flag for sample supernatant practical salinity, unitless, quality flag for sample supernatant practical salinity pH_BRINE, supernatant, 1, sample supernatant pH NBS scale pH_BRINE_uncertainty, uncertainty for sample supernatant pH NBS scale, 1, uncertainty for sample supernatant pH NBS scale pH_BRINE_quality_control, quality flag for sample supernatant pH NBS scale, unitless, quality flag for sample supernatant pH NBS scale PC_mass_flux, <1mm, mg m-2 d-1, particulate total carbon mass flux PC_mass_flux_uncertainty, uncertainty for particulate total carbon mass flux, mg m-2 d-1, uncertainty for particulate total carbon mass flux PC_mass_flux_quality_control, quality flag for particulate total carbon mass flux, unitless, quality flag for particulate total carbon mass flux PN_mass_flux, <1mm, mg m-2 d-1, particulate total nitrogen mass flux PN_mass_flux_uncertainty, uncertainty for particulate total nitrogen mass flux, mg m-2 d-1, uncertainty for particulate total nitrogen mass flux PN_mass_flux_quality_control, quality flag for particulate total nitrogen mass flux, unitless, quality flag for particulate total nitrogen mass flux POC_mass_flux, <1mm, mg m-2 d-1, particulate organic carbon mass flux POC_mass_flux_uncertainty, uncertainty for particulate organic carbon mass flux, mg m-2 d-1, uncertainty for particulate organic carbon mass flux POC_mass_flux_quality_control, quality flag for particulate organic carbon mass flux, unitless, quality flag for particulate organic carbon mass flux PIC_mass_flux, <1mm, mg m-2 d-1, particulate inorganic carbon mass flux PIC_mass_flux_uncertainty, uncertainty for particulate inorganic carbon mass flux, mg m-2 d-1, uncertainty for particulate inorganic carbon mass flux PIC_mass_flux_quality_control, quality flag for particulate inorganic carbon mass flux, unitless, quality flag for particulate inorganic carbon mass flux BSi_mass_flux, <1mm, mg m-2 d-1, particulate biogenic silicon mass flux BSi_mass_flux_uncertainty, uncertainty for particulate biogenic silicon mass flux, mg m-2 d-1, uncertainty for particulate biogenic silicon mass flux BSi_mass_flux_quality_control, quality flag for particulate biogenic silicon mass flux, unitless, quality flag for particulate biogenic silicon mass flux TIME_END, time sample closed, YYYY-MM-DD, time sample closed Reference, citable reference DOI, DOI

In collaboration with the Tasmanian State Emergency Service, water level monitoring instruments were installed to enable the collection of data in four estuaries identified as being vulnerable to coastal and compound flooding: Derwent Estuary, Huon Estuary, Georges Bay, and Macquarie Harbour. These instruments recorded fluctuations in water levels due to the combined influences of tide, river discharge, and weather events. The effects of the January 2022 Hunga Tonga-Hunga Ha’apai tsunami following a significant submarine volcanic explosion was also recorded in three out of the four estuaries. The datasets, comprising reduced water level observations, predicted water level, and residuals, are available from the IMAS Data Portal. Water level observations of varying duration were recorded between November 2020 – November 2022 for 14 sites in four Tasmanian estuaries. This work was undertaken by Karen Palmer as part of a PhD candidature at the University of Tasmania under the supervision of Dr Christopher Watson, Dr John Hunter, Assoc Prof Hannah Power (University of Newcastle), and Dr Rebecca Harris.

At the inception of our project, no study had examined particle fluxes in the Subantarctic Zone (SAZ) of the Southern Ocean, despite the fact that the SAZ represents a large portion of the total area of the Southern Ocean, serve as a strong sink for atmospheric (~1G t C yr-1 [Metzl et al., 1999]), and is central to hypotheses linking particle fluxes and climate change [Francois et al., 1997; Kumar et al., 1995; Sigman et al., 1999]. The SAZ serves as an interface between the cold nutrient-rich waters to its south and the nutrient-depleted subtropical gyres to its north. SAZ upper layers are marked by a thick layer of relatively homogenous Subantarctic Mode Water (SAMW), which overlies Antarctic Intermediate Water (AAIW). Both water masses are subducted northward beneath the subtropical gyres. Thus particles leaving the surface in these regions contribute to carbon redistribution via both the fraction that reaches the deep sea by settling and the fraction that is remineralized within SAMW or AAIW and subsequently subducted. The SAZ exhibits surface water carbon dioxide partial pressures well below atmospheric equilibrium, but PFZ waters are closer to atmospheric equilibrium in this sector [Metal et al., 1999; Poppet al., 1999]. The relative physical and biological contributions to these carbon dioxide partial pressure variations are unclear, but it is important to determine them because physical and biological carbon dioxide transfers are expected to show different responses to climate change [ Matear et al., 1999; Sarmiento and LeQuere, 1996]. For these reasons we focused on the SAZ and, for comparative purposes, on the PFZ to its south. We measured particle fluxes using moored sinking particle traps at three sites in the SAZ, in the PFZ, and beneath the Subantarctic Front (SAF), which separates them. This record describes particle flux data collected between 2004 and 2005. The NetCDF data contains the following variables. Please note not all variables are supplied in all files, specifically there are not uncertainty estimates and no quality control flags for this data. -----DATA DICTIONARY----- Name, description, units, standard name TIME, time, YYYY-MM-DD, time of sample midpoint TIME_START, time sample open, YYYY-MM-DD, time sample open NOMINAL_DEPTH, depth, m, nominal depth LATITUDE, latitude, degrees_north, latitude of anchor LONGITUDE, longitude, degrees_east, longitude of anchor pressure_actual, actual, dbar, actual pressure sample, sample number, 1, sample number sample_quality_control, quality flag for sample number, unitless, quality flag for sample number mass_flux, <1mm, mg m-2 d-1, particulate total mass flux mass_flux_uncertainty, uncertainty for particulate total mass flux, mg m-2 d-1,), uncertainty for particulate total mass flux mass_flux_quality_control, quality flag for particulate total mass flux, unitless, quality flag for particulate total mass flux SAL_BRINE, supernatant, 1, sample supernatant practical salinity SAL_BRINE_uncertainty, uncertainty for sample supernatant practical salinity, 1, uncertainty for sample supernatant practical salinity SAL_BRINE_quality_control, quality flag for sample supernatant practical salinity, unitless, quality flag for sample supernatant practical salinity pH_BRINE, supernatant, 1, sample supernatant pH NBS scale pH_BRINE_uncertainty, uncertainty for sample supernatant pH NBS scale, 1, uncertainty for sample supernatant pH NBS scale pH_BRINE_quality_control, quality flag for sample supernatant pH NBS scale, unitless, quality flag for sample supernatant pH NBS scale PC_mass_flux, <1mm, mg m-2 d-1, particulate total carbon mass flux PC_mass_flux_uncertainty, uncertainty for particulate total carbon mass flux, mg m-2 d-1, uncertainty for particulate total carbon mass flux PC_mass_flux_quality_control, quality flag for particulate total carbon mass flux, unitless, quality flag for particulate total carbon mass flux PN_mass_flux, <1mm, mg m-2 d-1, particulate total nitrogen mass flux PN_mass_flux_uncertainty, uncertainty for particulate total nitrogen mass flux, mg m-2 d-1, uncertainty for particulate total nitrogen mass flux PN_mass_flux_quality_control, quality flag for particulate total nitrogen mass flux, unitless, quality flag for particulate total nitrogen mass flux POC_mass_flux, <1mm, mg m-2 d-1, particulate organic carbon mass flux POC_mass_flux_uncertainty, uncertainty for particulate organic carbon mass flux, mg m-2 d-1, uncertainty for particulate organic carbon mass flux POC_mass_flux_quality_control, quality flag for particulate organic carbon mass flux, unitless, quality flag for particulate organic carbon mass flux PIC_mass_flux, <1mm, mg m-2 d-1, particulate inorganic carbon mass flux PIC_mass_flux_uncertainty, uncertainty for particulate inorganic carbon mass flux, mg m-2 d-1, uncertainty for particulate inorganic carbon mass flux PIC_mass_flux_quality_control, quality flag for particulate inorganic carbon mass flux, unitless, quality flag for particulate inorganic carbon mass flux BSi_mass_flux, <1mm, mg m-2 d-1, particulate biogenic silicon mass flux BSi_mass_flux_uncertainty, uncertainty for particulate biogenic silicon mass flux, mg m-2 d-1, uncertainty for particulate biogenic silicon mass flux BSi_mass_flux_quality_control, quality flag for particulate biogenic silicon mass flux, unitless, quality flag for particulate biogenic silicon mass flux TIME_END, time sample closed, YYYY-MM-DD, time sample closed Reference, citable reference DOI, DOI

Phytoplankton indirectly influence climate through their role in the ocean biological carbon pump. In the Southern Ocean, the subantarctic zone represents an important carbon sink, yet variables limiting phytoplankton growth are not fully constrained. Using three shipboard bioassay experiments on three separate voyages, we evaluated the seasonality of iron (Fe) and manganese (Mn) co-limitation of subantarctic phytoplankton growth south of Tasmania, Australia. We observed a strong seasonal variation in a phytoplankton Fe limitation signal, with a summer experiment showing the greatest response to Fe additions. An autumn experiment suggested that other factors co-limited phytoplankton growth, likely low silicic acid concentrations. The phytoplankton responses to Mn additions were subtle and readily masked by the responses to Fe. Using flow cytometry, we observed that Mn may influence the growth of some small phytoplankton taxa in late summer/autumn, when they represent an important part of the phytoplankton community. In addition, Mn induced changes in the bulk photophysiology signal of the spring community. These results suggest that the importance of Mn may vary seasonally, and that its control on phytoplankton growth may be associated with specific taxa.